Air is mostly (78% or so) nitrogen, and most of the rest is oxygen, so
you have most of air accounted for already. Air has lots of other stuff
in it at lower concentrations. There's carbon dioxide, water vapor,
argon, and neon. Plants need carbon dioxide for their metabolism. The
argon and neon are chemically inert, to a very good approximation.
In addition to the usual constituents of air, just about anything
that is in equilibrium with its vapor (or is a vapor) at standard
temperatures and pressures can be found in air at some places and
times, or perhaps everywhere if you're willing to look hard enough.
Methane is produced by bacteria decomposing biological material -- it's
often called "swamp gas". Alcohols and hydrocarbons evaporate and can
be found in the atmosphere. Manmade and natural pollutants include
oxides of nitrogen and sulfur. These latter can combine with water and
form nitric and sulfuric acid, which poison lakes (an effect called
"acid rain"). Carbon monoxide is a common pollutant produced by burning
fuels. Particulates are little bits of stuff that are suspended in the
air -- that is, they float and blow around until they settle on the
ground. Black, sooty smoke from burning coal, for instance, looks the
way it does because of all the little particulates in it. Ozone is also
a common pollutant found in urban areas. Aerosol sprays used to use
fluourocarbons which have now been banned, but they persist at a low
level in the atmosphere. Walk by a kitchen when dinner's cooking and
you'll be treated to a vast array of interesting molecules that smell
good but are present in the air at low concentrations, and usually only
at dinnertime.
The oxygen and nitrogen can be detected with the standard set of
experiments. Flammable stuff burns when there is oxygen, and doesn't
when all the oxygen is used up. A lot of the rest of the stuff can be
found by slowly freezing air and seeing what comes out.
Water vapor freezes first, leaving ordinary frost (or you can
condense it as a liquid, forming dew). Carbon dioxide freezes at a
colder temperature, but still much warmer than the oxygen or nitrogen,
and is stable as a solid at ordinary pressures. When the oxygen
liquifies out, the temperature is just over liquid nitrogen
temperature. Liquid oxygen, like its gas, also helps stuff burn, and
can be quite hazardous to handle. It's also paramagnetic, so you can
hold some between the poles of a (cold!) magnet.
Other stuff you can detect with your nose (sometimes), but there
are many hazardous gases which can poison you but which also do not
have any smell or color, so don't go sniffing unknown gases as a
science experiment. Various gas detectors and "sniffers" are
commercially available for detecting the concentrations of specific
components of air and pollutants. Oxygen meters are quite common, and
smog-check stations will put a detector in the tailpipe of a car to
detect various pollutants it is emitting.
Tom
(published on 10/22/2007)