Sodium ion Size
Most recent answer: 10/22/2007
Q:
Will you please explain why a na ion (+1) is smaller than a Na atom?
-derek
- DEREK KO (age 14)
Seoul
- DEREK KO (age 14)
Seoul
A:
Thats the results of the different orbital states that the
electrons can go into. Quantum mechanics implies that the stable states
an electron near a nucleus can be in dont have just any old size, but
a set of special sizes- sort of like the different ways that a drum can
vibrate ate fixed frequencies. Another implication is that at most two
electrons (with opposite spins) can occupy one of those orbital
states. The lowest energy ones fill up first. The states can be grouped
into shells which share, approximately, the same energy and size. A
soudium atom has just one to many electrons to fill a shell, so the
last one ends up in the next bigger shell. Stripping it off to make an
Na+ ion leaves only the smaller shell. Speaking of shells, I guess you might take all that as a short of shell game. Ive taken your question and moved it under the quantum mechanics shell. A more serious answer would try to develop the math behind the particular solutions, showing why the orbital shells exist and how many states are in each. That material is covered in a standard introductory quantum course. Mike W. |
(published on 10/22/2007)